Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid
Academic Article
Publication Date:
2024
abstract:
The accumulation of chiral ammonium-oxocarbenium dications in superacid is evidenced by low-temperature NMR spectroscopy, X-ray diffraction analysis and confirmed by DFT calculations. Its potential for the diastereoselective remote hydrofunctionalization of non-activated alkene is also explored.
Iris type:
1.1 Articolo in rivista
Keywords:
cations; fluorine; mechanisms; reaction; superelectrophile
List of contributors:
Berrino, Emanuela; Cantin, Thomas; Artault, Maxime; Beck, Stefanie; Jessen, Christoph; Marrot, Jérôme; Guégan, Frédéric; Mingot, Agnès; Kornath, Andreas; Thibaudeau, Sébastien
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